3,5-Bis(3-methylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate)
نویسندگان
چکیده
The asymmetric unit of the title N-heterocyclic carbene compound, C(17)H(22)N(4) (2+)·2PF(6) (-), consists of one N-heterocyclic carbene dication and two hexa-fluoro-phosphate anions. The two imidazole rings are twisted away from but to the same side of the central toluene ring, making dihedral angles of 76.69 (7) and 78.03 (7)° with the central ring. In the crystal, the components are linked by C-H⋯F interactions, generating a three-dimensional network.
منابع مشابه
Bis[μ2-1,2-bis(imidazol-1-ylmethyl)benzene-κ2 N 3:N 3′]bis[dichloridozinc(II)]
In the crystal structure of the centrosymmetric title compound, [Zn(2)Cl(4)(C(14)H(14)N(4))(2)], the Zn(II) atom is coordinated by two N atoms from two 1,2-bis-(imidazol-1-ylmeth-yl)benzene ligands and two Cl atoms to confer a distorted tetra-hedral geometry at the metal center.
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